Copper zinc tin sulfide cu2znsns4 or czts is a promising candidate as a sunlight absorbing layer in thin film solar cells. Temperature dependence of the open circuit voltage voc dominant carrier recombination mechanism can be obtained from the open circuit voltage vs. Characterization of a czts thin film solar cell grown by sputtering. This site is like a library, use search box in the widget to get ebook that you want. Pdf characterization of a czts thin film solar cell grown by.
Green synthesis of wurtzite copper zinc tin sulfide. Effect of calcination temperature on the properties of. Read czts absorber layer for thin film solar cells from electrodeposited metallic stacked precursors zncusn, applied surface science on deepdyve, the largest online rental service for scholarly research with thousands of academic publications available at your fingertips. Optimization of mocr bilayer back contacts for thinfilm. Controllable multinary alloy electrodeposition for thin. Silvaco simulating solar cell devices using silvaco tcad. The developed simulation software solves the coupled. Simulating solar cell devices using silvaco tcad tools. Surfactantfree czts nanoparticles as building blocks for. Publishers pdf, also known as version of record link back to dtu orbit citation apa.
Beginning with an overview and historical background of copper zinc tin sulphide czts technology, subsequent chapters cover properties of czts thin films, different preparation methods of czts thin films, a comparative study of czts and cigs solar cell, computational approach, and future applications of czts thin film solar modules to both groundmount and rooftop installation. Effect of absorber parameters on znsczts based solar cell effect of czts thickness. However, the practical aspects of controlling deposit morphology and composition have not been significantly addressed because of the complex coplating variables that still need to be understood for multinary alloy ed. However, there is still a need to develop lowcost and scalable synthesis methods. Characterization of a czts thin film solar cell grown by. A process route for the fabrication of solventredispersible, surfactantfree cu2znsns4 czts nanoparticles has been designed with the objective to have the benefit of a simple sulfide source which advantageously acts as i a complexing agent inhibiting crystallite growth, ii a surface additive providing redispersion in low ionic strength polar solvents and iii a transient. Pss for stable and efficient inverted perovskite solar cells.
The absorber layer thickness is a crucial parameter on the performance of thin film solar cells. It is composed of earth abundant, nontoxic elements. Today, energy is the key element of modern development 1. Although the dark are degraded with respect to the cztsse cell see main text, ff of the cztsse cell despite its lower voc. Cu2znsns4 czts is a prominent low cost absorber layer to be used as a substitute of cigs absorber layer in the thin film solar cells. Their findings reported stoichiometric composition of czts with the usage of citrate for electrodeposition. Molybdenum mo thin films are widely used as a back contact for photovoltaic devices such as cuin 1.
We performed centrifugation to screen the asmilled czts and obtain nanocrystals. Wurtzite czts could be considered as the derivative of wurtzite zns. Materials for renewable and sustainable energy, apr 2017. Copper zinc tin sulfide czts is a quaternary semiconducting compound which has received. Tcad modules required for solar cell simulation include. Efficiency enhancement of cu2znsns4 thin film solar cells. The quaternary compound cu2znsns4 czts gained considerable attention in the last decade due to its potential as an activelayer semiconductor for lowcost thinfilm solar cells. The application of kesterite in solar cells has attracted con. Electrodeposition ed technology is a lowcost industrial candidate for solar cell fabrication. Czts absorber layer for thin film solar cells from. The synthesis and characterization of thin film copper.
Solutionprocessed czts film is insitu synthesized on ito substrate compact czts thin film consists of about 1020 nm nanoparticles. Role of contact work function, back surface field, and. A solar cell, or photovoltaic cell in very early days also termed solar battery a denotation which nowadays has a totally different meaning, see here, is an electrical device that converts the energy of light directly into electricity by the photovoltaic effect, which is a physical and chemical phenomenon. The process involves synthesis of cuznsn composite oxide nanoparticles, preparation of composite oxide ink, deposition of composite oxide thin film and subsequent sulfurization treatment. However, despite the efforts and developments undertaken in recent years, the czts thin film solar cell efficiency is still far from the maximum theoretical efficiency. Thinfilm solar cells are commercially used in several technologies, including cadmium telluride cdte, copper indium gallium diselenide cigs, and amorphous thinfilm silicon asi, tfsi. Synthesis, deposition, and microstructure development of. The possible future prospects in the performance improvement of the czts based solar cell is analyzed in the present work with the.
Impact of molybdenum out diffusion and interface quality. An overview of solar cell technology mike mcgehee materials science and engineering global climate and energy projectglobal climate and energy project center for advanced molecular photovoltaics precourt institute stanford university konarka nanosolar john benner provided the slides with the nrel logo. A thinfilm solar cell is a second generation solar cell that is made by depositing one or more thin layers, or thin film tf of photovoltaic material on a substrate, such as glass, plastic or metal. We showed the applicability of these nanocrystal coatings for thin film solar cells by demonstrating a czts thin film solar cell using coatings annealed in a sulfur atmosphere. Cu 2znsns 4 czts, having the kesterite structure, is one of the most promising absorber layer candidates for low cost thin film solar cells. An alternative route towards lowcost cu2znsns4 thin film. Uppsala university, disciplinary domain of science and technology, technology, department of engineering sciences, solid state electronics. An overview of solar cell technology mike mcgehee materials science and engineering global climate and energy projectglobal climate and energy project center for advanced molecular photovoltaics precourt institute stanford university konarka nanosolar. The fabricated solar cell with s1 and s2 absorbers showed significant. It was confirmed that czts solar cells with high conversion efficiency existed in a relatively narrow composition region. Wurtzite copperzinctin sulfide as a superior counter electrode material for dyesensitized solar cells. Czts is a compound semiconductor that uses earthabundant elements. Zinc tin oxide zto is a potential buffer layer for the czts photocathode as it has shown to be a good interface with czts and such cztszto solar cells have shown comparable efficiencies with the cztscds solar cells.
Figure 3 shows tpv characteristics of the czts solar cell and estimated carrier lifetime plots. Wurtzite copperzinctin sulfide as a superior counter. Cts and czts for solar cells by pulsed laser deposition and pulsed electron deposition rebecca bolt ettlinger november 14, 2016 phd thesis supervisor. Cu2znsns4 czts is considered to be one of the most promising light absorbing materials for lowcost and highefficiency thinfilm solar cells. In this simulation, the czts thickness was varied from 0. The most promising result is the compound cu 2 znsns 4 czts, which is now a recognized potential material for the absorber layer in photovoltaic applications. Click download or read online button to get copper sun book now. Characteristics of insubstituted czts thin film and.
Fabrication of thin film czts solar cells with pulsed. The maximum efficiency reported for mixed sulfoselenide cztsse cell is 12. In this paper, the fabrication method of cztsbased thin film solar cells in our laboratory was stated briefly and the influence of the composition ratio on the photovoltaic properties were presented. The material is composed of nontoxic and earthabundant constituents, has optical properties suitable for photovoltaic application, and can be synthesized using a wide variety of methods. In the present study, wurtzite czts nanocone has been synthesized by a green chemistry route. We have utilized multivalent defects in the bulk of czts absorber layer to match our baseline solar cell to the experimentally reported czts solar cell 22. Abstracta nonvacuum and lowcost route to fabrication of cu2znsns4 czts thin film as absorber layer for thin film solar cell is demonstrated. Synthesis and characterization of kesterite cu2znsns4. A solar cell is an electronic device which directly converts sunlight into electricity. Read a mild hydrothermal route to synthesis of czts nanoparticle inks for solar cell applications, physica status solidi c current topics in solid state physics on deepdyve, the largest online rental service for scholarly research with thousands of academic publications available at. We conducted a systematic study of the factors controlling crystal growth and microstructure development during sulfidation annealing of films cast from colloidal.
Improvement of mocu2znsns4 interface for cu2znsns4 czts thin film solar cell application volume 1638 hongtao cui, xiaolei liu, xiaojing hao, fangyang liu, ning song, wei li, chang yan, gavin conibeer, martin green. Role of contact work function, back surface field and. An overview of solar cell technology stanford university. Light shining on the solar cell produces both a current and a voltage to generate electric power. Comprehensive characterization and modelling of operation. Czts solar cell s and s elements individual and combined s. The surface recombination velocity srv used at left contact are 105 cms for electron and 107 cms for. Each of the first three quarters of the subcontract has been detailed in quarterly reports. Effect of calcination temperature on the properties of czts absorber layer prepared by rf sputtering for solar cell applications. Performance of cztsmapbi 3 solar cells remarkably depends on czts film thickness czts film thinner than 100 nm is a more effective htm in cztsmapbi 3 solar cells czts is better than pedot. Traditional siliconbased solar cells use crystalline silicon produced with heavy equipment, making the sibased solar cells relatively expensive.
Pdf on jan 28, 2019, abdellah benami and others published effect of czts parameters on photovoltaic solar cell from numerical. Development and characterization of copper zinc tin. The back contact is the first layer to be deposited and its properties have significant effects on the solar cell performance. Improvement of mocu2znsns4 interface for cu2znsns4 czts. The sandwichtype solar cell was assembled by placing the czts ce on the n719 dyesensitized photoelectrode working electrode and clipped together as an open cell for measurements.
In the present contribution a znocdsczts structure with new thicknesses of the different layers has been proposed using solar cell capacitance simulator. Study of czts and cztsse solar cells for buffer layers. Cu2znsns4 czts is a promising candidate material for photovoltaic applications. Fabrication of cu2znsns4 czts nanoparticle inks for. Spisces, blaze, luminous, tft, device3d, luminous3d and tft3d 1. The characterization methods consist of various optical and electrical measurements on solar cells in steadystate, transient and frequency domain. Cigs and cdte are two of the most promising thinfilm solar cells and have recently seen growing.
Cu2znsns4 czts, having the kesterite structure, is one of the most promising absorber layer candidates for low cost thin film solar cells, because of its suitable. The crystal cell kesterite czts is analogous to the vertical enlarged binary zincblende zns. We determined the electrical junction ej locations in cuin,gase 2 cigs and cu 2 znsnse 4 czts solar cells with 20. Scaps has been used to simulate multivalent defect occurring in chalcopyrite and chalcogenide solar cell materials.
Impact of excess and disordred sn sites on cu2znsns4 absorber. The solar cell efficiency in czts was increased to 5. Effect of czts parameters on photovoltaic solar cell from. If you continue browsing the site, you agree to the use of cookies on this website. Czts is comprised of earth abundant and nontoxic elements, and power conversion efficiencies in czts based solar cells have risen quickly. In this work, we fabricated czts nanocrystal inks by a wet ball milling method, with the use of only nontoxic solvents, followed by filtration.
The benefits of czts include the abundant and inexpensive sup. The exponential decay of the photovoltage with respect to time directly represents the faster. The influence of the composition ratio on cztsbased thin. Various types of solar cell technologies and current trends of development 2 16.
Copper zinc tin sulfide based thin film solar cells. Cu 2 znsns 4 czts based devices has become increasingly popular due to the better efficiency with different architectures for various types of solar cells. The development of a cuznsns czts based low cost solar cell to make a device by creating advanced material. Czts solar cell device simulation with varying absorber thickness.
Vacuum deposited copper zinc tin sulfide czts thin film. In this final report highlights of the first three quarters will be provided and details will be given of the final quarter. Major problems in czts where tsm can help 1 why is the voc low. Polycrystalline silicon solar cell polysi or mcsi polycrystalline pv modules are generally composed of a number of different crystals, coupled to one another in. In the czts study, kesterite is the form generally used and is easy to synthesize, which includes a tetragonal cell crystal 15, 18, 37. In this study10, a citrate complex system was used to fabricate czts on glassftozns, for the fabrication of thin film solar cells the surface. We report the performance of cu2znsns4 czts thin film solar cell that showed efficiency in the. Effect of absorber parameters on zns czts based solar cell effect of czts thickness. Czts solar cells have achieved comparitively low record ef.
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